Orbs and Spheres are used in crafting for creating various items. Many of them however have no use at all.
Naming Conventions
You can tell a lot just from the name of your orb or sphere.
1. The name starts depending upon Tier:
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2. Then there is a variant name, usually either "of Pure" and "of Distilled". There is also "of Tainted", which seems to have vanished from the game (Tainted Orb of Magic on Exchange 04/22/2013), and "of Dark", which seems to have no use yet.
3. Finally, the last word depends upon the craft trade:
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Example
Therefore, for example, a "Shimmering Orb of Distilled Power", is a distilled crafting ingredient of Tier 3 for Outfitter.
Uses
Orbs and Spheres are used for special recipes.
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Sources
Pure Orbs (Blue - Uncommon) drop en masse from harvesting and item deconstruction, can be bought from the Exotic Crafting Merchant, and drop occasionately from Set and Batch Work Order rewards.
Distilled Orbs (Green - Common) can be bought from the Exotic Crafting Merchant and drop occasionately from Set and Batch Work Order rewards.
Tainted Orbs (Yellow - Rare) no longer drop at all. (Tainted Orb of Magic on Exchange 04/22/2013)
Dark Orbs (Orange - Heroic) drop sometimes from item deconstruction of heroic and better items.
Orbs
Tier 2 - Amateur
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Tier 3 - Apprentice
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Spheres
Tier 4 - Initiate
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Tier 5 - Journeyman
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origional information from vgcrafters